Title : Total synthesis of (-)-virginiamycin M2: application of crotylsilanes accessed by enantioselective Rh(II) or Cu(I) promoted carbenoid Si-H insertion.

Pub. Date : 2011 Dec 16

PMID : 22070230






1 Functional Relationships(s)
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1 This reagent, which was prepared via a Rh(II)- or Cu(I)-catalyzed carbenoid Si-H insertion, was used to introduce the desired olefin geometry and stereocenters of the C1-C5 propionate subunit. Alkenes Rh blood group D antigen Homo sapiens