Title : Theoretical and infrared spectroscopy study of the conformational preferences for some 3-monosubstituted-2-methylpropenes.

Pub. Date : 2011 Oct 15

PMID : 21723185






2 Functional Relationships(s)
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1 For second-period atoms bonded to C-3, two or more conformers are observed in CCl(4) solution, but when substitution by heavier atoms takes place, only one conformer is observed under the tested conditions, i.e., the gauche form with respect to the C=C-C-X dihedral angle. Carbon complement C3 Homo sapiens
2 For second-period atoms bonded to C-3, two or more conformers are observed in CCl(4) solution, but when substitution by heavier atoms takes place, only one conformer is observed under the tested conditions, i.e., the gauche form with respect to the C=C-C-X dihedral angle. Carbon complement C3 Homo sapiens