Title : Mixed phosphane η5-CpRuCl(PR3)2 complexes as ambifunctional catalysts for anti-Markovnikov hydration of terminal alkynes.

Pub. Date : 2011 Jun 1

PMID : 21553862






1 Functional Relationships(s)
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1 The catalytic activity of [CpRu(L)(2)(MeCN)]PF(6) (L = 2-diphenylphosphinopyridine with bulky groups at C-6) for anti-Markovnikov hydration of terminal alkynes to aldehydes is retained when one heterocyclic ligand L is replaced by L" = PPh(3). Aldehydes sperm associated antigen 17 Homo sapiens