Title : Metal-dependent phase selection in coordination polymers derived from a C(2V)-symmetric tricarboxylate.

Pub. Date : 2010 Jun 7

PMID : 20455576






2 Functional Relationships(s)
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1 The addition of Cu to reactions with Co(II), Fe(III), or Mn(II) leads to the formation of heterobimetallic UMCM-150 isostructural analogues Co(1)Cu(2)(BHTC)(2) (4), Fe(1)Cu(2)(BHTC)(2) (5), and Mn(1)Cu(2)(BHTC)(2) (6) containing both paddlewheel and trinuclear metal clusters. Copper mitochondrially encoded cytochrome c oxidase II Homo sapiens
2 The addition of Cu to reactions with Co(II), Fe(III), or Mn(II) leads to the formation of heterobimetallic UMCM-150 isostructural analogues Co(1)Cu(2)(BHTC)(2) (4), Fe(1)Cu(2)(BHTC)(2) (5), and Mn(1)Cu(2)(BHTC)(2) (6) containing both paddlewheel and trinuclear metal clusters. Copper mitochondrially encoded cytochrome c oxidase II Homo sapiens