Title : Cobalt(II)-catalyzed intramolecular C-H amination with phosphoryl azides: formation of 6- and 7-membered cyclophosphoramidates.

Pub. Date : 2010 Mar 19

PMID : 20184343






1 Functional Relationships(s)
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1 A highly effective Co(II)-based system has been developed for catalytic intramolecular C-H amination with phosphoryl azides without the need of terminal oxidant or other additives, resulting in the high-yielding production of cyclophosphoramidates with nitrogen gas as the byproduct. Nitrogen mitochondrially encoded cytochrome c oxidase II Homo sapiens