Title : Cyanide lability and linkage isomerism of hexacyanochromate(III) induced by the Co(II) ion.

Pub. Date : 2010 Jan 18

PMID : 20000485






1 Functional Relationships(s)
Download
Sentence
Compound Name
Protein Name
Organism
1 Results obtained by a combination of X-ray crystallography, infrared spectroscopy, and magnetometry provide unequivocal evidence that the presence of certain Lewis acids (e.g., Co(II) in this work and Fe(II) ions and BPh(3) in previously reported studies) promote the process of cyanide linkage isomerism, which, in the case of Co(II) species, leads to facile labilization of cyanide ligands from the [Cr(CN)(6)](3-) anion. ammonium ferrous sulfate mitochondrially encoded cytochrome c oxidase II Homo sapiens