Title : Unusual electronic structure of first row transition metal complexes featuring redox-active dipyrromethane ligands.

Pub. Date : 2009 Oct 14

PMID : 19807183






1 Functional Relationships(s)
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1 Structural and magnetic characterization (SQUID, EPR) of the bis-pyridine adducts of (dpm)Mn(II)(py)(2), (dpm)Fe(II)(py)(2), and (dpm)Co(II)(py)(2) reveal each divalent ion to be high-spin and pseudotetrahedral in the solid state, whereas the (dpm)Ni(II)(py)(2) is low-spin and adopts a square-planar geometry. ammonium ferrous sulfate mitochondrially encoded cytochrome c oxidase II Homo sapiens