Title : DAST-mediated regioselective anomeric group migration in saccharides.

Pub. Date : 2009 Jun 5

PMID : 19441783






1 Functional Relationships(s)
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1 When saccharides bearing a sulfur, selenium, or oxygen substituent at the anomeric center and an unprotected hydroxyl group either at C-4 or C-6 were subjected to fluorination with DAST in dichloromethane, a regioselective migration of the anomeric substituent to the C-4 or C-6 position was observed. Methylene Chloride complement C6 Homo sapiens