Title : Complexation of late transition metal(II) ions (M = Co, Ni, Cu, and Zn) by a macrocyclic thiacrown ether studied by means of electrospray ionization mass spectrometry.

Pub. Date : 2009 Jun

PMID : 19399766






1 Functional Relationships(s)
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1 The large selectivity is ascribed to the redox-active nature of copper which enables a reduction from Cu(II) to Cu(I), occurring upon ESI-MS, whereas Co(II), Ni(II) and Zn(II) cannot undergo similar redox reactions. Copper mitochondrially encoded cytochrome c oxidase II Homo sapiens