Title : Substituent effects on regioselectivity in the autoxidation of nonconjugated dienes.

Pub. Date : 2009 Apr 22

PMID : 19331391






2 Functional Relationships(s)
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1 Increasing size of the substituents at C-1 and C-5 of the diene favors kinetic products arising from oxygen addition at the nonconjugated position, C-3, of the pentadienyl radical intermediate. Oxygen complement C3 Homo sapiens
2 Groups at C-1 and C-5 of the diene can influence product distribution based upon (a) steric demand in the oxygen-radical reaction and (b) the influence of substituents on the rearrangement of the C-3 peroxyl radical to give conjugated diene products. Oxygen complement C3 Homo sapiens