Title : Raising the ceiling of diastereoselectivity in hydrogen transfer on acyclic radicals.

Pub. Date : 2009 Mar 20

PMID : 19226157






2 Functional Relationships(s)
Download
Sentence
Compound Name
Protein Name
Organism
1 We report here that the monodentate complexation of Me2AlCl to an ester group significantly enhances the selectivity of hydrogen transfer on acyclic radicals flanked by both an ester functionality and a stereogenic center, leading to C-2,C-3-anti products with high diastereoselectivity. Esters complement C2 Homo sapiens
2 We report here that the monodentate complexation of Me2AlCl to an ester group significantly enhances the selectivity of hydrogen transfer on acyclic radicals flanked by both an ester functionality and a stereogenic center, leading to C-2,C-3-anti products with high diastereoselectivity. Esters complement C2 Homo sapiens