Title : Synthesis of 5-hydroxycyclopent-2-enones from allenyl vinyl ketones via an interrupted Nazarov cyclization.

Pub. Date : 2009 Mar 19

PMID : 19215105






1 Functional Relationships(s)
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1 Hydrolysis of the ester with methanol and basic alumina provides, in good to excellent overall yield, a 5-hydroxycyclopent-2-enone in which the alcohol is predominantly trans to a substituent at C-4. Esters complement C4A (Rodgers blood group) Homo sapiens