Title : Facile dichloromethane activation and phosphine methylation. Isolation of unprecedented zwitterionic organozinc and organocobalt intermediates.

Pub. Date : 2009 Feb 28

PMID : 19214306






2 Functional Relationships(s)
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1 Both C-Cl bonds of CH(2)Cl(2) are readily activated by CoCl(2) and metallic Zn allowing quantitative methylation of phosphines; unprecedented zwitterionic Co(ii) and Zn(ii) intermediates have been characterized which display alpha-metallated phosphoniums. Methylene Chloride mitochondrially encoded cytochrome c oxidase II Homo sapiens
2 Both C-Cl bonds of CH(2)Cl(2) are readily activated by CoCl(2) and metallic Zn allowing quantitative methylation of phosphines; unprecedented zwitterionic Co(ii) and Zn(ii) intermediates have been characterized which display alpha-metallated phosphoniums. Methylene Chloride mitochondrially encoded cytochrome c oxidase II Homo sapiens