Title : Studies on the Condensation Pathway to and Properties of Diiron Azadithiolate Carbonyls.

Pub. Date : 2007

PMID : 18592045






2 Functional Relationships(s)
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1 DNMR experiments show that the free energies of activation for rotation of the amide bond are the same for Fe(2)[(SCH(2))(2)NAc](CO)(6) and Fe(2)[(SCH(2))(2)NAc](CO)(4)(PMe(3))(2), which implies that the ligands on the iron centers do not strongly affect the basicity of the nitrogen. ammonium ferrous sulfate synuclein alpha Homo sapiens
2 DNMR experiments show that the free energies of activation for rotation of the amide bond are the same for Fe(2)[(SCH(2))(2)NAc](CO)(6) and Fe(2)[(SCH(2))(2)NAc](CO)(4)(PMe(3))(2), which implies that the ligands on the iron centers do not strongly affect the basicity of the nitrogen. ammonium ferrous sulfate synuclein alpha Homo sapiens