Title : Redox active cage for the electrochemical sensing of anions.

Pub. Date : 2008 Jun 2

PMID : 18386923






1 Functional Relationships(s)
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1 Anion inclusion in an aqueous MeCN solution induces a distinct cathodic shift of the potential of the CoIII/CoII couple, whose magnitude decreases along the series: Cl->Br- approximately NCO->I- approximately NCS-, which reflects anion tendencies to receive H-bonds from the receptor. acetonitrile mitochondrially encoded cytochrome c oxidase II Homo sapiens