Title : Effects of magnesium salts and amines on the stereoselectivity in the imine aldol reaction.

Pub. Date : 2007 Dec

PMID : 18057758






1 Functional Relationships(s)
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1 In the imine aldol reactions of 1 with aromatic aldehydes using magnesium salts in the presence of amines, the threo/erythro ratios of products increased in the order Mg(ClO4)2>MgI2>MgBr2>MgCl2>Mg(OTf)2 and N,N,N",N"-tetramethylethylenediamine (TMEDA)>Et3N. Amines POU class 2 homeobox 2 Homo sapiens