Title : Mechanism of nitrite formation by nitrate photolysis in aqueous solutions: the role of peroxynitrite, nitrogen dioxide, and hydroxyl radical.

Pub. Date : 2007 Aug 29

PMID : 17676847






2 Functional Relationships(s)
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1 Photolysis of aqueous NO3(-) with lambda > or = 195 nm is known to induce the formation of NO2(-) and O2 as the only stable products. Nitrogen Dioxide NBL1, DAN family BMP antagonist Homo sapiens
2 This is, in part, due to photoisomerization of NO3(-) to ONOO(-) at lambda < 280 nm, followed by the formation of *OH and *NO2 through the decomposition of ONOOH (pKa = 6.5-6.8). Nitrogen Dioxide NBL1, DAN family BMP antagonist Homo sapiens