Title : Ruthenium-catalyzed cycloisomerization-6pi-cyclization: a novel route to pyridines.

Pub. Date : 2007 Apr 12

PMID : 17362020






1 Functional Relationships(s)
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1 The unsaturated ketones and aldehydes derived from the cycloisomerization of primary and secondary propargyl diynols in the presence of [CpRu(CH3CN)3]PF6 (1) are converted to 1-azatrienes which in turn undergo a subsequent electrocyclization-dehydration to provide pyridines with excellent regiocontrol. Aldehydes sperm associated antigen 17 Homo sapiens