Title : Solvent-modulated reversible conversion of a [2 x 2]-grid into a pincer-like complex.

Pub. Date : 2007 Jan 21

PMID : 17299624






1 Functional Relationships(s)
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1 The triazine derived ligand reacts with one equivalent of Co(II) salts to give complexes whose architecture depends on the solvent employed: the [2 x 2]-grid like tetranuclear complex and the pincer-like mononuclear complex, obtained respectively by crystallization from nitromethane and from acetonitrile may be interconverted reversibly, the grid-pincer conversion being markedly accelerated by adding an amine. acetonitrile mitochondrially encoded cytochrome c oxidase II Homo sapiens