Title : Hydrogen-atom transfer in open-shell organometallic chemistry: the reactivity of Rh(II)(cod) and Ir(II)(cod) radicals.

Pub. Date : 2007

PMID : 17219454






1 Functional Relationships(s)
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1 EPR spectroscopy, X-ray diffraction, and DFT calculations reveal that each of these [M(II)(cod)(N-ligand)](2+) species adopts a square-pyramidal geometry with the two cod double bonds and the two pyridine fragments in the basal plane and the N(amine) donor at the apical position. Amines small nuclear ribonucleoprotein polypeptides B and B1 Homo sapiens