Title : C-H bond activation of arenes by a transient eta2-cyclopropene niobium complex.

Pub. Date : 2006 Dec 20

PMID : 17165710






1 Functional Relationships(s)
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1 The intermolecular C-H bond activation of benzene occurs under very mild conditions (room temperature) via a rare stereospecific 1,3-H addition on an unsaturated eta2-cyclopropene intermediate generated by a beta-H abstraction of CH4 from TpMe2NbMe(c-C3H5)(MeCCMe) to give TpMe2NbPh(c-C3H5)(MeCCMe). Benzene DNA polymerase iota Homo sapiens