Title : Palladium-catalyzed decarboxylative aza-Michael addition-allylation reactions between allyl carbamates and activated olefins. Generation of quaternary carbon adjacent to secondary amine carbon center.

Pub. Date : 2006 Sep 1

PMID : 16930053






1 Functional Relationships(s)
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1 The reaction of allyl carbamates with activated olefins in the presence of Pd(PPh3)4 catalyst in THF proceeded smoothly at room temperature to give the corresponding beta,alpha-bisadducts, beta-amino-alpha-allylated products, in high yields. Alkenes caveolin 1 Homo sapiens