Title : Uranyl extraction by beta-diketonate ligands to SC-CO2: theoretical studies on the effect of ligand fluorination and on the synergistic effect of TBP.

Pub. Date : 2005 Jan 13

PMID : 16851014






2 Functional Relationships(s)
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1 (iv) Concentrated solutions of UO(2)L(2)(TBP) complexes at the CO(2)-water interface display an equilibrium between adsorbed and extracted species, and the proportion of extracted species is larger with F- than with H- ligands, in agreement with experimental observations. co(2) TATA-box binding protein Homo sapiens
2 Thus, TBP plays a dual synergistic role: its co-complexation by UO(2)L(2) yields a hydrophobic and CO(2)-philic complex suitable for extraction, whereas TBP in excess at the interface facilitates the migration of the complex to the supercritical phase. co(2) TATA-box binding protein Homo sapiens