Title : Use of the tetrahydroborate ligand as "gate-keeper" and protected hydride ligand: preparation and study of alkyl hydride and acyl hydride complexes of ruthenium(II).

Pub. Date : 2006 Jun 14

PMID : 16804578






1 Functional Relationships(s)
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1 Successive treatment of [Ru(eta2-BH4)(CO)HL2], , with ethene and then CO yields propanal, but turning this into a catalytic cycle is hindered by the greater readiness of to yield propanal non-catalytically (reacting with CO) than catalytically (reacting with H2). Hydrogen DNA polymerase iota Homo sapiens