Title : A new approach to promoting sluggish Diels-Alder reactions: dihapto-coordination of the diene.

Pub. Date : 2006 Feb 8

PMID : 16448094






1 Functional Relationships(s)
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1 The eta2-bound metal is thought to promote a Michael reaction between the uncoordinated portion of the diene and the enone, and the resulting enolate then closes to form the cycloalkene product. Metals DNA polymerase iota Homo sapiens