Title : The first buckybowl aryne. Corannulyne: a nonplanar benzyne.

Pub. Date : 2005 Oct 27

PMID : 16235942






1 Functional Relationships(s)
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1 [reaction: see text] Treatment of bromocorannulene with NaNH(2)/tBuOK in THF in the presence of furans or amines leads to formation of addition products in good yields, presumably through formation of 1,2-didehydrocorannulene (corannulyne). tert-butoxide, potassium neuraminidase 1 Homo sapiens