Title : Zirconium sandwich complexes with eta(9) indenyl ligands: well-defined precursors for zirconocene-mediated coupling reactions.

Pub. Date : 2004 Dec 29

PMID : 15612732






2 Functional Relationships(s)
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1 In contrast to bis-cyclopentadienyl chemistry, the olefin adducts of the bis-indenyl zirconium sandwiches undergo preferential C-H activation to yield the corresponding allyl hydride compounds, although reaction with excess olefin proceeds through the eta(2)-olefin adduct, forming the corresponding zirconacyclopentane. Alkenes DNA polymerase iota Homo sapiens
2 In contrast to bis-cyclopentadienyl chemistry, the olefin adducts of the bis-indenyl zirconium sandwiches undergo preferential C-H activation to yield the corresponding allyl hydride compounds, although reaction with excess olefin proceeds through the eta(2)-olefin adduct, forming the corresponding zirconacyclopentane. Alkenes DNA polymerase iota Homo sapiens