Title : A new chiral Rh(II) catalyst for enantioselective [2 + 1]-cycloaddition. mechanistic implications and applications.

Pub. Date : 2004 Jul 28

PMID : 15264821






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1 A novel chiral Rh(II) catalyst (1) is introduced for the [2 + 1]-cycloaddition of ethyl diazoacetate to terminal acetylenes and olefins with high enantioselectivity. Alkenes Rh blood group D antigen Homo sapiens