Pub. Date : 2004 Jun 23
PMID : 15198611
1 Functional Relationships(s)Download |
Sentence | Compound Name | Protein Name | Organism |
| 1 | Electronic structure calculations using density functional theory (DFT) reveal that the enhanced reaction rate for [L(8)py(2)Ni(SAr)](+) is rooted in a four-electron repulsion (or a "filled/filled interaction") between a completely filled nickel(II) d(pi) orbital and one of the two thiolate frontier orbitals, a condition that is absent in the Fe(II) and Co(II) complexes. | ammonium ferrous sulfate | mitochondrially encoded cytochrome c oxidase II | Homo sapiens |