Title : Using stereoelectronic effects to explain selective reactions of 4-substituted five-membered ring oxocarbenium ions.

Pub. Date : 2004 Jun 10

PMID : 15176819






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1 [reaction: see text] The utility of the inside attack model to predict and analyze the stereoselectivities of nucleophilic additions to complex five-membered ring oxocarbenium ions is demonstrated in a systematic study of C-4-substituted acetals. oxocarbenium complement C4A (Rodgers blood group) Homo sapiens