Title : Interaction of nitrogen oxides with sublimed layers of (meso-tetraphenylporphyrinato)cobalt(II); IR evidence of oxo-transfer from (nitro)porphyrinatocobalt(III) to free nitric oxide.

Pub. Date : 2003 Dec 15

PMID : 14658904






3 Functional Relationships(s)
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1 Interaction of a low-pressure NO2 with sublimed layers of (meso-tetraphenylporphyrinato)cobalt(II) (Co(TPP)) leads to formation of 5-coordinate nitro complex Co(III)(TPP)(NO2). Nitrogen Dioxide mitochondrially encoded cytochrome c oxidase III Homo sapiens
2 Interaction of a low-pressure NO2 with sublimed layers of (meso-tetraphenylporphyrinato)cobalt(II) (Co(TPP)) leads to formation of 5-coordinate nitro complex Co(III)(TPP)(NO2). Nitrogen Dioxide mitochondrially encoded cytochrome c oxidase III Homo sapiens
3 Upon exposure of these layers to pyridine vapors, the fast reaction with formation of 6-coordinate nitro-pyridine porphyrins (Py)Co(III)(TPP)(NO2) occurs. Nitrogen Dioxide mitochondrially encoded cytochrome c oxidase III Homo sapiens