Title : Acrylate formation via metal-assisted C-C coupling between CO2 and C2H4: reaction mechanism as revealed from density functional calculations.

Pub. Date : 2003 Dec 3

PMID : 14640662






1 Functional Relationships(s)
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1 The formation of the new C-C bond is shown to take place via oxidative coupling of coordinated CO(2) and C(2)H(4) ligands resulting in a metalla-lactone intermediate, which can rearrange to an agostic species allowing for a beta-hydrogen shift process. co(2) amyloid beta precursor protein Homo sapiens