Title : cis-stereoselective nickel-catalyzed cyclization/alkylation and arylation reactions of allenyl-aldehydes and -ketones with organozinc reagents.

Pub. Date : 2002 Nov 21

PMID : 12510273






1 Functional Relationships(s)
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1 Highly stereoselective alkylative and arylative cyclization reactions of allenyl-aldehydes and -ketones with organozinc reagents occur efficiently in the presence of catalytic Ni(COD)2 to afford cis-fused homoallylic cyclopentanols. Ketones COD2 Homo sapiens