Title : Development of a new Lewis acid-catalyzed [3,3]-sigmatropic rearrangement: the allenoate-Claisen rearrangement.

Pub. Date : 2002 Nov 20

PMID : 12431073






1 Functional Relationships(s)
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1 This reaction, which is contingent upon the use of Lewis acid, can be conducted with a range of metal salts (Yb(OTf)3, AlCl3, Sn(OTf)2, Cu(OTf)2, MgBr2.Et2O, FeCl3, Zn(OTf)2) with catalyst loadings as low as 5 mol %. ferric chloride POU class 2 homeobox 2 Homo sapiens