Title : Beta-scission of side-chain alkoxyl radicals on peptides and proteins results in the loss of side-chains as aldehydes and ketones.

Pub. Date : 2002 Jun 1

PMID : 12031901






1 Functional Relationships(s)
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1 Recently, initial attack on Ala side-chains was shown to give alpha-carbon radicals (and hence backbone cleavage) and formaldehyde, via the formation and subsequent beta-scission, of C-3 alkoxyl radicals. Alanine complement C3 Homo sapiens