Title : Anhydrodihydroartemisinin and its 10-trifluoromethyl analogue: access to novel d-ring-contracted artemisinin trifluoromethyl ketones.

Pub. Date : 2002 Feb 22

PMID : 11846670






1 Functional Relationships(s)
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1 When treated with hexafluoro-2-propanol or trifluoroethanol, 11 readily underwent a rearrangement yielding to the D-ring-contracted trifluoromethyl ketone 9alpha with retention of configuration at C-9. Trifluoroethanol complement C9 Homo sapiens