Title : Studies of silyl-accelerated 1,5-hydrogen migrations in vinylcyclopropanes.

Pub. Date : 2001 Dec 28

PMID : 11749603






1 Functional Relationships(s)
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Protein Name
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1 cis-1-Silylmethyl-2-vinylcyclopropanes 17 and 19 undergo facile 1,5-hydrogen transposition upon mild thermolysis in benzene or toluene solution (80-110 degrees C) to give nearly quantitative yields of ring-opened 1-silyl-1,4-diene products. Toluene suppressor of cytokine signaling 1 Homo sapiens