Title : Metal Complex-Catalyzed Epoxidation of Olefins by Dioxygen with Co-Oxidation of Aldehydes. A Mechanistic Study.

Pub. Date : 1996 Feb 14

PMID : 11666283






1 Functional Relationships(s)
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1 It is concluded from this study that the principal role of the metal complexes is to aid in the initiation step for the free radical autoxidation of the aldehyde and that acylperoxy radicals generated in the autoxidation reaction (or metal complexes formed by complexation of the acylperoxy radicals) are the active epoxidizing agents. Metals activation induced cytidine deaminase Homo sapiens