Title : Unexpected products via singlet oxygen oxygenation of functionalized 5,6-dihydro-1,4-oxathiins

Pub. Date : 2000 May 4

PMID : 10810708






1 Functional Relationships(s)
Download
Sentence
Compound Name
Protein Name
Organism
1 Unexpected products via singlet oxygen oxygenation of functionalized 5,6-dihydro-1,4-oxathiins [formula: see text] Single oxygen oxygenation of 5,6-dihydro-1,4-oxathiins substituted at C-3 with an electron-withdrawing group leads stereoselectively to ketosulfoxides 5 and 6, instead of the expected dicarbonyl compounds 3. Oxygen complement C3 Homo sapiens